Use the `png_jmpbuf' accessor, as recommended since libpng 1.4.0:
http://www.libpng.org/pub/png/src/libpng-1.2.x-to-1.4.x-summary.txt .

--- plotutils-2.6/libplot/z_write.c	2013-07-12 17:19:12.000000000 +0200
+++ plotutils-2.6/libplot/z_write.c	2013-07-12 17:19:07.000000000 +0200
@@ -164,7 +164,7 @@ _pl_z_maybe_output_image (S___(Plotter *
     }
 
   /* cleanup after libpng errors (error handler does a longjmp) */
-  if (setjmp (png_ptr->jmpbuf))
+  if (setjmp (png_jmpbuf (png_ptr)))
     {
       png_destroy_write_struct (&png_ptr, (png_info **)NULL);
       return -1;
@@ -444,7 +444,7 @@ _our_error_fn_stdio (png_struct *png_ptr
 #endif
     }
 
-  longjmp (png_ptr->jmpbuf, 1);
+  longjmp (png_jmpbuf (png_ptr), 1);
 }
 
 static void 
